
I enjoy yoga. At right is a closeup of a section of my very first yoga mat. It came as part of one of those kits, with the DVD and everything, that you find in your local discount store.
As a materials person, I am intrigued by this structure. I thought I'd share it here.
This mat is probably PVC, wholly or in part. PVC stands for polyvinyl chloride. It is a thermoplastic polymer, a type of plastic. PVC in itself is non-toxic. Without additives, it has the feel of vinyl siding on houses. Many of the PVC products, however, have been softened with the use of plasticizers called phthalates. Phthalate is toxic to humans and other critters. It outgasses for awhile after the softened PVC has been manufactured. (That "new car smell", for example.) Most plastics manufacturers have ceased using phthalates in PVC construction. If you're concerned, ask about the additives used.
All that is well and good to know. However, I always like to find out the microstructure of these beasties. It is fascinating to me to think how the tiny structure has emergent properties at higher levels of complexity. In other words, a monomer molecule of PVC ain't nothing like the real thing, baby.
The aforementioned monomer is a carbon atom with 3 single bonds to hydrogen, and one to chlorine. But there is so much more!
When you get a bunch of these puppies together, they form chains of inert molecules. Multiple chains conglomerate like spaghetti noodles in a bowl. The ability of the chains to slip past one another accounts for the softness/hardness of the material. You can do stuff to change the hardness. Raising the temperature makes it soft. Lowering, hardens it. But there is yet more!
If you bubble the clumps of chains by blowing air through them (think blowing bubbles in your drink with a straw, but with 10 x the force and an 100 x smaller straw), you can create plastic bubbles! Tiny bubbles, everywhere. Like the foam on a glass of milk, the bubbles in plastic form their own structure, depending on a host of factors.
Plastic bubbles don't collapse as liquid bubbles do. Plastics are, after all, not liquid at room temperature. However, they do reshape over time. New bubbles are roundish. Established bubbles are polygon-shaped. Foam is born.
I'm no plastics engineer, but I find this stuff fascinating. Somebody figured out how to blow bubbles in PVC to form foams that stay foamy! Like the yoga mats in their original incarnation. Current mats are made of many different materials, not all of which are plastics.
Next time I'm doing a down dog, I will no doubt be looking at a spot on my mat like the one shown, imagining blowing bubbles in my spaghetti that stay!
It is great to be a geek.